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Bis[(1Z,3Z)-1,3-bis­(4-fluoro­phen­yl)-N,N′-diphenyl­propane­diiminato]magnesium(II)

✍ Scribed by Huang, Bor-Hunn ;Peng, Ya-Liu ;Lin, Chu-Chieh

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
168 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Mg(C 27 H 19 F 2 N 2 ) 2 ], the Mg II atom, lying on a crystallographic twofold rotation axis, is tetrahedrally coordinated by four N atoms from two diiminate ligands.

metal-organic papers m1978

Huang et al. [Mg(C 27 H 19 F 2 N 2 ) 2 ]

📜 SIMILAR VOLUMES

Bis{N-[(1Z,3Z)-1,3-bis(4-fluorophenyl)-3
Bis{N-[(1Z,3Z)-1,3-bis(4-fluorophenyl)-3-(phenylimino)prop-1-enyl]aniline(1–)}zinc(II)
✍ Peng, Ya-Liu ;Hsueh, Mao-Lin ;Lin, Chu-Chieh 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 930 KB

In the title complex, [Zn(C 27 H 19 F 2 N 2 ) 2 ], a twofold rotation axis passes through the Zn atom, which is tetrahedrally coordinated by four N atoms from two diketiminate ligands.

4-(4,4-Diphenyl­buta-1,3-dien­yl)-N,N-bi
4-(4,4-Diphenyl­buta-1,3-dien­yl)-N,N-bis­(4-methyl­phen­yl)aniline
✍ Wu, An-Shu ;Li, Xiang-Gao ;He, Li-Li ;Wang, Shi-Rong 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 361 KB

The molecular structure of (I), with the atom numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.

Bis{N-[(Z)-4-(3-methyl-5-oxo-1-phenyl-1H
Bis{N-[(Z)-4-(3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl­idene)(phen­yl)meth­yl]naphthyl­amido-κ2N,O}iron(II)
✍ Ma, Rong-Ming ;Sun, Shao-Fa ;Bao, Feng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 227 KB

The Fe II atom in the title compound, [Fe(C 27 H 20 N 3 O) 2 ], is N,O-chelated by two deprotonated 3-methyl-4-[(1-naphthylamino)(phenyl)methylene]-1-phenyl-1H-pyrazol-5(4H)-one ligands in a severely distorted tetrahedral geometry.