Bis(1,5-cyclooctadiene) copper(I) tetrafluoroborate
โ Scribed by Stanley E. Manahan
- Publisher
- Elsevier Science
- Year
- 1967
- Weight
- 116 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0020-1650
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๐ SIMILAR VOLUMES
shows that the strength of the arsenic-chlorine bond increases [2.04+2.59 mdyne/A] in the transition AsCl3+AsOCI3, exactly as in the system PCI3+POCl3 [2.34-+2.98 mdyne/A]. The compounds are therefore also related in the details of their bonding. AsOCI3 slowly decomposes at -25"C, and much more rap
An electron spin resonance study at temperatures between 300 and 4 K demonstrates that the two crystallographically inequivalent Cu(ll) sites in the title compound are subject to different Jahn-Teller behaviour. It is shown that this is not induced by cooperative interactions between the Jahn-Teller
Polyphenylacetylene, in good yields and with high molecular weight, has been obtained using three new Rh based catalytic systems, i.e. [Rh(COD)(SC6Fs)]2, [Rh(COD)(SC6Hs)]2 and Rh(SC 6 F 5)(P4~3)(COD) where COD = 1,5-cyclooctadiene. t H-and 13C-NMR spectra have shown that the polyphenylacetylene obta