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Two different copper sites in hexakis(1-methyltetrazole)copper(II) bis(tetrafluoroborate)

✍ Scribed by P.E.M. Wijnands; W.J.A. Maaskant; J. Reedijk

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 377 KB
Volume: 130
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80253-6

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✦ Synopsis

An electron spin resonance study at temperatures between 300 and 4 K demonstrates that the two crystallographically inequivalent Cu(ll) sites in the title compound are subject to different Jahn-Teller behaviour. It is shown that this is not induced by cooperative interactions between the Jahn-Teller sites but arises from the different lattice symmetries of the two sites.

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