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Bis(1,4-di-tert-butyl-1,4-diazabutadiene)copper(i) [(3,6-di-tert-butyl-o-benzosemiquinono)(3,6-di-tert-butyl-catecholato)cuprate(ii)]. The molecular structure and intramolecular electron transfer

✍ Scribed by G. A. Abakumov; A. V. Krashilina; V. K. Cherkasov; I. L. Eremenko; S. E. Nefedov


Book ID
110332994
Publisher
Springer
Year
2001
Tongue
English
Weight
377 KB
Volume
50
Category
Article
ISSN
1573-9171

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✍ R. J. Waltman; J. Bargon πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 505 KB

## Abstract Hyperfine splitting constants are reported for radical anions of the azulene derivatives 1‐__tert__‐butyl‐, 1,3‐di‐__tert__‐butyl‐ and 4,6,8‐trimethylazulene. Radical anion geometries are optimized at the Hartree‐Fock level of theory using 3–21G and 3–21 + G\* basis sets. The perimeter