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Bis­[1,2-bis­(di­phenyl­phosphino)­ethene]­nickel(II) diperchlorate

✍ Scribed by Li, Yi-Zhi ;Liu, Jia-Cheng ;Qu, Jian-Qiang ;Wang, Liu-Fang ;Xia, Chun-Gu ;Niu, Jian-Zhong

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
318 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Ni(C 26 H 22 P 2 ) 2 ](ClO 4 ) 2 , the Ni atom lies on an inversion centre and is square-planar coordinated by four P atoms from two bidentate ligands. The average NiÐP bond length is 2.2374 (7) A Ê .

📜 SIMILAR VOLUMES

[1,2-Bis­(di­phenyl­phosphino)­ethane]­d
[1,2-Bis­(di­phenyl­phosphino)­ethane]­di­bromo­nickel(II) tetra­hydro­furan solvate
✍ Beaudoin, Sophie ;Zargarian, Davit ;Bélanger-Gariépy, Francine ;Fontaine, Frédér 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 269 KB

Acta Cryst. (2001). E57, m433±m434 slightly longer in the THF adduct than the corresponding distances in the CH 2 Cl 2 adduct [2.141 (1) and 2.156 (1) A Ê ], but both NiÐBr bonds are very similar. In this structure, there is a stacking interaction between the THF ring and the C121Ð C126 phenyl ring,

{2,6-Bis­[(di­phenyl­phosphino)­methyl]­
{2,6-Bis­[(di­phenyl­phosphino)­methyl]­phenyl}chloro­platinum(II)
✍ Fischer, Steffen ;Wendt, Ola F. 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 223 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.027 wR factor = 0.041 Data-to-parameter ratio = 26.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.