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Bis-(polyfluoroalkyl)-acetylenes. V. Addition of Bis-(trifluoromethyl)-1,2-dithietene to Olefins and Acetylenes 1

✍ Scribed by Krespan, C. G.; McKusick, B. C.


Book ID
126842282
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
422 KB
Volume
83
Category
Article
ISSN
0002-7863

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A new electrophilic addition to acetylen
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Acetylenes react with bis(pyridine)iodo(I) tetrafluoroborate (1) in the presence of a wide variety of nucleophiles (F,Cl,Br,I,SCN,pyridine,OAc,anisole,H) to give 1,2iodofunctionalized olefins (4).