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Bis (2,4,6,8-cyclononatetraen-1-yl)methane

✍ Scribed by Gabriele Sabbioni; Markus Neuenschwander


Publisher
John Wiley and Sons
Year
1985
Tongue
German
Weight
305 KB
Volume
68
Category
Article
ISSN
0018-019X

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✦ Synopsis


Bis (2,4,6,8‐cyclononatetraen‐1‐yl)methanes

Bis (2,4,6,8‐cyclononatetraen‐1‐yl)methanes (2a–c) have been prepared by reaction of all‐cis‐cyclononatetraenide with 1,1‐dichlorodimethyl ether as well as with carbenium ion precursors 9b and 9c. The title compounds 2 are attractive precursors of highly delocalised nonafulvenes of type 3; however, elimination experiments 2→3 failed so far.


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