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8a.9a-Diaza-perhydroanthracen aus Di-piperidon-(2)-yl-(6)-methan

โœ Scribed by Birkofer, Leonhard ;Engels, Hans Dieter


Publisher
Wiley (John Wiley & Sons)
Year
1962
Tongue
English
Weight
455 KB
Volume
95
Category
Article
ISSN
0009-2940

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Synthesis of carbon-14 labelled cis-2-am
โœ M. B. Gopinathan; J. A. Kepler ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› John Wiley and Sons ๐ŸŒ French โš– 183 KB

The synthesis of the title compound (3) is described. Treatment of a solution of triethyl [14C]orthoformate in dry chloroform with cis-[4-(2,5-diamino-6-chloro-4-pyrimidinyl) -amino] -2cyclopentenyl]carbinol (1) afforded crude 2. Hydrolysis of crude 2 with 2 N sodium Eydroxide gave 3 in 34% overall