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Biradical mechanism of the 1,2-bond shift reaction catalysed by vitamin B12 coenzyme

โœ Scribed by Valia Amir-Ebrahimi; John J Rooney


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
124 KB
Volume
164
Category
Article
ISSN
1381-1169

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Bond-shift rearrangement during hydrogen
โœ Valia Amir-Ebrahimi; John J. Rooney ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 323 KB

The hydrogenolysis of neopentyl iodide on reduced Co or Pt dispersed on MgO support yields increasing amounts of 2-metylbutane and 2-methylbutenes in addition to neopentane, as the temperature is raised from 50 to 150ยฐC. These results support the idea that a n-complexed half-reaction state is simult