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Biosynthetic Origin of a Branched Chain Analogue of the Lipase Inhibitor, Lipstatin

✍ Scribed by Eisenreich, Wolfgang; Kupfer, Ernst; Stohler, Peter; Weber, Wolfgang; Bacher, Adelbert

Book ID
117992090
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
141 KB
Volume
46
Category
Article
ISSN
0022-2623

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The biosynthesis of the tetrahydropyranyl side chain of verucopeptin (1) in cultures of Actinomadura verrucosospora was investigated. Incorporation experiments using 13C-labeled acetate and propionate, followed by analysis of the labeled metabolite by NMR, revealed that the tetrahydropyranyl side ch