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Biosynthesis of phytosterols in the pea. Mode of incorporation of carbon-2 hydrogen atoms of mevalonic acid into sitosterol

✍ Scribed by Sliwowski, Jacek K.; Caspi, Eliahu


Book ID
127179462
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
968 KB
Volume
99
Category
Article
ISSN
0002-7863

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## Abstract Incorporation of (3R)‐[(5R)‐5‐^3^H]‐mevalonate into verrucarin followed by hydrolyses to verrucarol (2) and transformation of the latter to the spirolactol 5 and the spirolactone 6 successively, demonstrate the identity of the C(11)‐hydrogen of the trichothecane skeleton with the 5β€β€˜pro