✦ LIBER ✦

Biosynthesis of the Verrucarins and Roridins. Part 4. The mode of incorporation of (3R)-[(5R)-5-3H]-mevalonate into verrucarol. Evidence for the identity of the C(11)-hydrogen atom of the trichothecane skeleton with the (5R)-hydrogen atom of (3R)-mevalonic acid

✍ Scribed by Beat Müller; Christoph Tamm

Publisher: John Wiley and Sons
Year: 1975
Tongue: German
Weight: 392 KB
Volume: 58
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19750580217

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✦ Synopsis

Abstract

Incorporation of (3R)‐[(5R)‐5‐^3^H]‐mevalonate into verrucarin followed by hydrolyses to verrucarol (2) and transformation of the latter to the spirolactol 5 and the spirolactone 6 successively, demonstrate the identity of the C(11)‐hydrogen of the trichothecane skeleton with the 5‐‘pro‐R’ hydrogen atom of (3R)‐mevalonate.

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