Biosynthesis of macrolides. 5. Regiochemistry of the labeling of lasalocid A by [13C,18O]-labeled precursors
โ Scribed by Hutchinson, C. Richard; Sherman, Mary M.; Vederas, John C.; Nakashima, Thomas T.
- Book ID
- 126226789
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 500 KB
- Volume
- 103
- Category
- Article
- ISSN
- 0002-7863
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Incorporation of 13C-labelled acetates and methionine, 14C and ZH-labelled ethyl 3,5-dimethylorsellinate into terretonin (5) by cultures of Aspergillus terreus indicated that its biosynthesis proceeds via a mixed polyketide-terpenoid (meroterpenoid) pathway. Incorporation of 1803 gas and ethyl 3,5-d
## Abstract A potato plant has been grown in a closed chamber with CO~2~ enriched to a level of 31 at. % in ^13^C as the sole source of carbon. In 80 days the plant produced 1,684 g of tubers labeled with 29 at. % ^13^C. of the carbon fixed by the potato plant appromixately 70% was found in the tub