𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Biosynthesis of biotin in microorganisms: IV. Repression and derepression of (+)-biotin synthesis from (±)-desthiobiotin

✍ Scribed by Chik H. Pai; Herman C. Lichstein


Book ID
118845320
Publisher
Elsevier Science
Year
1966
Tongue
English
Weight
681 KB
Volume
114
Category
Article
ISSN
0003-9861

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NMR studies on chiral intermediates in t
✍ Wen-xue Chen; Ping Zhang; Fen-er Chen 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 138 KB

## Abstract The chemical structure and stereochemistry of 12 intermediates in the total synthesis of (+)‐biotin starting from D‐mannose as chiral pool were completely assigned using one‐ and two‐dimensional NMR experiments, including 1D selective NOE, DEPT, COSY, HSQC and HMBC. Copyright © 2010 Joh