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Bioorganic synthesis in reverse micelles and related systems

✍ Scribed by Natalia L. Klyachko; Andrey V. Levashov

Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
295 KB
Volume
8
Category
Article
ISSN
1359-0294

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πŸ“œ SIMILAR VOLUMES

Enzymatic synthesis of oligopeptides in
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Some oligopeptide derivatives were successfully synthesized in 56-88% yield by ctchymotrypsin in AOT-Brij30/n-heptane mixed reverse micelles. The reaction conditions such as W0 value, reaction time and the concentration of enzyme in the water pool were studied with ZTyrGlyGlyOEt as model peptide.

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Nucleotide coupling was investigated in reverse micelles formed by (cety1)trimethylammonium bromide (CTAB), in hexane/pentan-1-01. In particular, the coupling of 2'-deoxy-5'-0-methylcytidine 3'-0-phosphate, prepared by phosphoramidite chemistry, with 5'-amino-5'-deoxythymidine was studied in the pre