Biomimetic total synthesis of polycitrin A
✍ Scribed by Andreas Terpin; Kurt Polborn; Wolfgang Steglich
- Book ID
- 107857616
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 375 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0040-4020
No coin nor oath required. For personal study only.
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## Abstract **Vom Teil zum Ganzen**: Die erste Totalsynthese des natürlich vorkommenden Diterpens Pallavicinolid A ist gelungen. Besonders hervorzuheben sind drei biomimetische Umwandlungen: eine basenunterstützte Grob‐Fragmentierung, eine Singulettsauerstoff‐Oxidation und eine intramolekulare Diel