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Biomimetic synthesis of neodihydrothebaine and bractazonine from thebaine

โœ Scribed by Hubert G. Theuns; Guus F. La Vos; Michael C. ten Noever de Brauw; Cornelis A. Salemink

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
130 KB
Volume
25
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Photochemical irradiation of the morphinan alkaloid thebaine l_, followed by reduction, affords the dibenz[d,f]azonine alkaloids neodihydrothebaine 2 and bractazonine 3, in a sequence paralleling the proposed biosynthesis of these alkaloids in Papaver bracteatum. Recently, we reported the finding of two unusual alkaloids in Papaver bracteatum

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