Evidence has been found for the presence of an oxazoline ring in a siderophore from Paracoccus ohitrificans. This requires revision of the previously assigned structure for this compound. Siderophores, defined as high affinity ferric ion transport agents from microbial sources may, in general, be gr
โฆ LIBER โฆ
Biomimetic synthesis of a Paracoccus denitrificans siderophore analog
โ Scribed by Bergeron, Raymond J.; Burton, Philip S.; Kline, Steven J.; McGovern, Kathy Ann
- Book ID
- 127085423
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 995 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0022-3263
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N-(Trifluoroacetyl)dehydrodipeptides 2-3 were coupled to aminomethylene dimethylacetal derivatives 4-5. The resulting pseudo-tripeptides 6 were stepwise deprotected (carbonyl function (7) then amine function) and in situ cyclized into imidazolopyrazines 1.