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Biomimetic oxovanadium(IV) and (V) complexes with a tridentate (N,N,O)-donor hydrazonic ligand. Two X-ray crystal structure modifications of (2-acetylpyridine-benzoylhydrazonato)dioxovanadium(V)

✍ Scribed by Pedro Ivo da S. Maia; Victor M. Deflon; Elizeu J. de. Souza; Edgardo Garcia; Gerimário F. de. Sousa; Alzir A. Batista; Alberthmeiry T. de. Figueiredo; Elke Niquet

Book ID
106546896
Publisher
Springer
Year
2005
Tongue
English
Weight
270 KB
Volume
30
Category
Article
ISSN
0340-4285

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Oxovanadium(IV, V) Complexes with 2-Acet
Oxovanadium(IV, V) Complexes with 2-Acetylpyridine-2-furanoylhydrazone (Hapf) as Ligand. X-Ray Crystal Structures of [VO2(apf)] and [V2O2(μ-O)2(apf)2]
✍ Victor M. Deflon; Daniela M. de Oliveira; Gerimário F. de Sousa; Alzir A. Batist 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 105 KB 👁 1 views

The preparation of oxovanadium(IV,V) coordination compounds with 2-acetylpyridine-2-furanoylhydrazone (Hapf) is described. [VO(apf)(acac)] was prepared from oxovanadium(IV) diacetylacetonate [VO(acac) 2 ] by reaction with Hapf in methanol or dichloromethane. The complex is paramagnetic and its EPR s