Biologically Inspired Hierarchical Design of Nanocomposites Based on Poly(ethylene oxide) and Cellulose Nanofibers
✍ Scribed by Sutheerat Changsarn; James D. Mendez; Kadhiravan Shanmuganathan; E. Johan Foster; Christoph Weder; Pitt Supaphol
- Book ID
- 102497630
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 385 KB
- Volume
- 32
- Category
- Article
- ISSN
- 1022-1336
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Attempts to create hierarchically structured, uniaxially oriented nanocomposites comprising cellulose nanowhiskers (CNWs), which promise anisotropic mechanical properties, are exceedingly rare. We report here the fabrication of uniaxially‐oriented arrays of microfibers based on poly(ethylene oxide) (PEO) and CNWs by electrospinning. Compared with the neat PEO fibers, the incorporation of CNWs within the fibers increased the storage modulus (E′) of arrays along the fiber axis of the PEO/CNW nanocomposite fibers. Successful incorporation of the CNWs within each of the as‐spun PEO/CNW nanocomposite fibers in the direction parallel to the fiber axis was verified by both scanning and transmission electron microscopy. magnified image
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## Abstract Degradable dendrimer‐like PEOs were designed using an original ABC‐type branching agent featuring a cleavable ketal group, following an iterative divergent approach based on the anionic ring opening polymerization (AROP) of ethylene oxide and arborization of PEO chain ends. A seventh ge