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Biologically Inspired Hierarchical Design of Nanocomposites Based on Poly(ethylene oxide) and Cellulose Nanofibers

✍ Scribed by Sutheerat Changsarn; James D. Mendez; Kadhiravan Shanmuganathan; E. Johan Foster; Christoph Weder; Pitt Supaphol


Book ID
102497630
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
385 KB
Volume
32
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

Attempts to create hierarchically structured, uniaxially oriented nanocomposites comprising cellulose nanowhiskers (CNWs), which promise anisotropic mechanical properties, are exceedingly rare. We report here the fabrication of uniaxially‐oriented arrays of microfibers based on poly(ethylene oxide) (PEO) and CNWs by electrospinning. Compared with the neat PEO fibers, the incorporation of CNWs within the fibers increased the storage modulus (E′) of arrays along the fiber axis of the PEO/CNW nanocomposite fibers. Successful incorporation of the CNWs within each of the as‐spun PEO/CNW nanocomposite fibers in the direction parallel to the fiber axis was verified by both scanning and transmission electron microscopy. magnified image


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