## Dendrolasinl was synthesized from farnesol via biogenetic-type intermediates. ## Farnesol(J) was converted to epoxyfarnesol(3) under standard Sharpless conditions. 2 Lithium diethylamide in boiling benzene cleanly converted 3 to triene-
β¦ LIBER β¦
Biogentic-type synthesis of cularine
β Scribed by T. Kametani; K. Fukumoto; M. Fujihara
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 751 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0045-2068
No coin nor oath required. For personal study only.
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## Abstract In order to study the cularine biosynthesis, Lβ[Ξ²β^13^C]tyrosine (Lβ18), [Ξ±β^13^C]tyramine (20), Lβ[3β²β^18^O]DOPA (Lβ19) and [Ξ±β^13^C, 3β²β^18^O]dopamine (21) were synthesized and fed to __Corydalis claviculata__ and __Sarcocapnos crassifolia__ plants, which are rich sources of cularineβ