✦ LIBER ✦

Biogenetically patterned synthesis of Δ8(9-capnellene

✍ Scribed by Alan M. Birch; Gerald Pattenden

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 164 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87002-1

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✦ Synopsis

In abiogenetlcally patterned synthesis, treatment of the cycloocta-1,5-drene (3b) or its exo-methylene Isomer (41, with boron trlfluorlde etherate is shown to lead to A8(g)-capnellene (8).

Capnellane 1s the generic name applied to the group of trlcycllc sesquiterpene alcohols (15 -e) and the hydrocarbon (21, isolated from the

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