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Biogenetic-type synthesis of vepridimerines A–D

✍ Scribed by J.Foyere Ayafor; B.Lucas Sondengam; Joseph D. Connolly; David S. Rycroft


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
225 KB
Volume
26
Category
Article
ISSN
0040-4039

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Biogenetic-like synthesis of d,1-hirsute
✍ Yasufumi Ohfune; Haruhisa Shirahama; Takeshi Matsumoto 📂 Article 📅 1976 🏛 Elsevier Science 🌐 French ⚖ 123 KB

Hirsutene is a tricyclic sesquiterpene hydrocarbon isolated from Coriolus censors and its structure was determined as shown in formula 101 h . The biosynthetic pathway' to hirsutene\* has been suggested to involve a sequence of rearrangements depicted in Scheme I. we now wish to describe a chemical