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Biocatalytic oxidative kinetic resolution of sec-alcohols: stereocontrol through substrate-modification

✍ Scribed by Wolfgang Stampfer; Birgit Kosjek; Kurt Faber; Wolfgang Kroutil


Book ID
104359588
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
188 KB
Volume
14
Category
Article
ISSN
0957-4166

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Catalytic asymmetric and chemoselective
✍ Kouta Masutani; Tatsuya Uchida; Ryo Irie; Tsutomu Katsuki πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 209 KB

Optically active (nitroso)(salen)ruthenium(II) chloride (2) was found to be an ecient catalyst for aerobic oxidation of racemic secondary alcohols under irradiation with a halogen or Β―uorescent lamp, which proceeded with good enantiomer-dierentiation (k rel =11Β±20). Furthermore, no epoxidation was o