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Biocatalytic Approaches toward the Synthesis of Both Enantiomers of trans -Cyclopentane-1,2-diamine

✍ Scribed by Luna, Amparo; Alfonso, Ignacio; Gotor, Vicente


Book ID
126165886
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
48 KB
Volume
4
Category
Article
ISSN
1523-7060

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✍ Frank W. Curtius; Hans-Dieter Scharf πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 304 KB

Both enantiomers of the title compound are synthesized for the first time in four steps including a [2+2]-photocycloaddition to build up the cyclobutane backbone and a cerium supported reductive permethylation. During the cerium supported process a complete and selective change in the configuration