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Binuclear Pentalene Iron Carbonyl Complexes

โœ Scribed by Huidong Li; Hao Feng; Weiguo Sun; Yaoming Xie; R. Bruce King; Henry F. Schaefer III


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
849 KB
Volume
2011
Category
Article
ISSN
1434-1948

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โœ David Tetard; Jean-Baptiste Verlhac ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 773 KB

## Binuclear manganese(III/IV) or iron(III/III) complexes efficiently functionalize cyclohexane using hydroperoxides or peracids as oxidants. A mechanistic study clearly demonstrate the role of dioxygen gas in these hydroxylation reactions. Moreover, it was demonstrated that the cleavage of the pe