Binuclear Homoleptic Manganese(III,III)
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Andreas Geisselmann; Peter Klüfers; Bernd Pilawa
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Article
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1998
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John Wiley and Sons
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English
⚖ 113 KB
Just a "reducing" sugar-namely, D-mannose-is a starting material in the synthesis of a mixed-valence complex of manganese in the oxidation states +III and +IV. Ba [Mn Mn (β-D-ManfH ) ]Cl⋅14 H O (Manf=mannofuranose; the structure of the anion is shown on the right) is prepared in aqueous solution by