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Binuclear manganese(III, IV) complexes

✍ Scribed by Rafael Usón; Victor Riera; Mariano Laguna


Book ID
105299620
Publisher
Springer
Year
1975
Tongue
English
Weight
446 KB
Volume
1
Category
Article
ISSN
0340-4285

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Binuclear Homoleptic Manganese(III,III)
✍ Andreas Geisselmann; Peter Klüfers; Bernd Pilawa 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 113 KB

Just a "reducing" sugar-namely, D-mannose-is a starting material in the synthesis of a mixed-valence complex of manganese in the oxidation states +III and +IV. Ba [Mn Mn (β-D-ManfH ) ]Cl⋅14 H O (Manf=mannofuranose; the structure of the anion is shown on the right) is prepared in aqueous solution by