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Electron delocalization in binuclear manganese(III/IV) complexes with di-μ-oxo bridges

✍ Scribed by Takashi Okuno; Yuzo Nishida

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
353 KB
Volume
15
Category
Article
ISSN
0277-5387

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Mechanistic disparity in the electron transfer reactions of thiosulfate with di-μ-oxo-bis(1,4,8,11-tetraazacyclotetradecane)-dimanganese(III,IV) and di-μ-oxo-bis(1,4,7,10-tetraazacyclododecane)-dimanganese(III,IV) complexes
✍ Anangamohan Panja; Nizamuddin Shaikh; Pradyot Banerjee; Basudeb Saha 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 132 KB

## Abstract A comparative kinetic study of the reactions of two mixed valence manganese(III,IV) complexes of macrocyclic ligands, [L^1^Mn^IV^(O)~2~Mn^III^L^1^], **1** (L^1^ = 1,4,8,11‐tetraazacyclotetradecane) and [L^2^Mn^IV^(O)~2~Mn^III^L^2^], **2** (L^2^ = 1,4,7,10‐tetraazacyclododecane) with thi