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Binuclear Magnesium, Calcium and Zinc Complexes Based on Bis(salicylaldimine) Ligands with Rigid Bridges

✍ Scribed by Sven Range; Dirk F.-J. Piesik; Sjoerd Harder


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
501 KB
Volume
2008
Category
Article
ISSN
1434-1948

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Binuclear Magnesium, Calcium, and Zinc C
✍ Dirk F. -J. Piesik; Robert Stadler; Sven Range; Sjoerd Harder 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 519 KB

## Abstract The diprotic bis(salicylaldimine) ligand __N__,__N′__‐bis(3,5‐di‐__t__Bu‐salicylidene)diimine, (1‐NN)H~2~, was smoothly deprotonated by reaction with two equivalents of a metal amide M[N(SiMe~3~)~2~]~2~ (M = Mg, Ca or Zn) to form a bimetallic metal amide complex (1‐NN)[MN(SiMe~3~)~2~]~2