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Copper(II) and Zinc(II) Complexes with a Photoactive Bridging Ligand Based on Carbazole: Synthesis, Structures, Electronic and Magnetic Properties

✍ Scribed by Eike T. Spielberg; Winfried Plass

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
605 KB
Volume
2011
Category
Article
ISSN
1434-1948

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## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~