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Binding of phosphonate chelating agents and pyrophosphate to apotransferrin

โœ Scribed by Harris, Wesley R.; Nesset-Tollefson, Diane

Book ID
127270646
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
819 KB
Volume
30
Category
Article
ISSN
0006-2960

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## Abstract To aid in designing new therapeutic iron chelating agents, the mechanism of iron binding to prototypic heterocyclic carboxaldehyde thiosemicarbazones has been studied. Based on molecular orbital and spectroscopic studies, iron (II) is found to bind in a covalent manner, while iron(III)