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Binding between Ground-State Aluminum Ions and Small Molecules: Al + ·(H 2 /CH 4 /C 2 H 2 /C 2 H 4 /C 2 H 6 ) n . Can Al + Insert into H 2 ?

✍ Scribed by Kemper, Paul R.; Bushnell, John; Bowers, Michael T.; Gellene, Gregory I.

Book ID
127351782
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
121 KB
Volume
102
Category
Article
ISSN
1089-5639

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New high-level quantum chemical calculations have been undertaken to understand the rates and mechanisms of the reactive and associative channels for the reactants C2H2(+) + H2. The reactive channel, which produces C2H3(+) + H, has been shown to be slightly endothermic, confirming earlier calculatio