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BINAP/1,4-Diamine—Ruthenium(II) Complexes for Efficient Asymmetric Hydrogenation of 1-Tetralones and Analogues.

✍ Scribed by Takeshi Ohkuma; Tomonori Hattori; Hirohito Ooka; Tsutomu Inoue; Ryoji Noyori

Publisher
John Wiley and Sons
Year
2004
Weight
42 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract Two novel tridentate ruthenium(II) complexes containing an asymmetric heteroaromatic and a polyamine ligand, [Ru(dipn)(dptp)](ClO~4~)~2~ (**1**⋅2 $\rm{ ClO\_4^ -}$) and [Ru(dipn)(pat)](ClO~4~)~2~ (**2**⋅2 $\rm{ ClO\_4^ -}$) (dipn=__N__‐(3‐aminopropyl)propane‐1,3‐diamine; dptp=2‐(5,6‐dip