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Bimetallic AgPt and AuPt aggregates synthesized by radiolysis

✍ Scribed by S. Remita; M. Mostafavi; M.O. Delcourt

Book ID
118415156
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
415 KB
Volume
47
Category
Article
ISSN
0969-806X

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Pt and Pt/Cu carbonyl clusters synthesiz
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✍ B. Le Gratiet; H. Remita; G. Picq; M.O. Delcourt 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 473 KB

In the mixed solvent: 50/50% v/v water/2-propanol, [Pt3(CO)6]2n -clusters with n = 3 10 have been obtained by irradiating solutions containing K2PtCI 4 under 1 atm CO. n is deduced from the very typical UV-visible and IR absorption spectra. The reduction occurs by a combined effect of CO and of the