Selective hydrogenation catalyzed by polymer-protected PdPt and PdAu bimetallic clusters
✍ Scribed by Masafumi Harada; Naoki Toshima
- Book ID
- 103956304
- Publisher
- Elsevier Science
- Year
- 1991
- Weight
- 66 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0923-1137
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Metal clusters [1][2][3] with sizes smaller than 2 nm have discrete electronic structures due to quantum size effects, and exhibit various properties such as optical absorption in the visible and near-infrared regions, [4][5][6] photoluminescence, [7,8] two-photon absorption, [9] and paramagnetism,
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A polymer-protected PtlCo bimetallic colloid with a molar ratio of 3:l has been prepared by a polyol process. Over the above PtlCo bimetallic colloid catalyst, cinnamaldehyde can be selectively hydrogenated to cinnamyl alcohol with 99.8% selectivity at 96.2% conversion.