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Bildung von 1,2-Dioxolanen aus Cyclopropanen

✍ Scribed by Rücker, Gerhard ;Frey, Klaus


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
446 KB
Volume
1987
Category
Article
ISSN
0947-3440

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Synthese von Triafulven-Vorstufen aus tr
✍ Andreas Weber; Gabriele Sabbioni; Roberto Galli; Urs Stämpfli; Markus Neuenschwa 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 German ⚖ 529 KB

## Synthesis of Triafulvene-Precursors from Trisubstituted Cyclopropaues Trisubstituted cyclopropanes 5a-f are prepared by carhene addition to the appropriate olefins. While 5a (Y = OAc) and 5c (Y = Cl) rearrange in the presence of BuLi, 5d (Y = SPh) is stable enough to allow the envisaged sequenc