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Bifunctionalization of a mixture of 2-chloro-and 2-bromo-N-ethoxycarbonylmethylpyridinium halides by arylmethylidenemalononitriles in basic medium

✍ Scribed by Tverdokhleb, N. M.; Khoroshilov, G. E.; Zubatyuk, R. I.; Shishkin, O. V.


Book ID
120652344
Publisher
Springer US
Year
2013
Tongue
English
Weight
523 KB
Volume
49
Category
Article
ISSN
0009-3122

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Rate constants, k, were determined for the solvolytic reactions of 2-bromo-2-methylbutane, 2-chloro-2methylbutane and 3-chloro-3-methylpentane in 10 pure diols at 298.15 K. The Gibbs energies of activation were calculated in order to study the influence of the solvent and to provide mechanistic info