Kinetic and thermodynamic study of 2-bro
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LΓdia C. Albuquerque; Luisa C. Moita; Ana N. SimΓ΅es; Raquel C. GonΓ§alves; EugΓ©ni
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Article
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1998
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John Wiley and Sons
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English
β 91 KB
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Rate constants, k, were determined for the solvolytic reactions of 2-bromo-2-methylbutane, 2-chloro-2methylbutane and 3-chloro-3-methylpentane in 10 pure diols at 298.15 K. The Gibbs energies of activation were calculated in order to study the influence of the solvent and to provide mechanistic info