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Bicyclo[4.2.2]deca-1,5-diene, a bridgehead diene

✍ Scribed by Wiseman, John R.; Vanderbilt, Jeffrey J.

Book ID: 126397358
Publisher: American Chemical Society
Year: 1978
Tongue: English
Weight: 273 KB
Volume: 100
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00492a050

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## Abstract From the NO‐ and O~2~‐dependence of the trapping rate of 1,6‐cyclodecadiyne (3) in the gas phase and in supercritical CO~2~ in the temperature range 160–290°C, the enthalpy profile for the equilibrium 3 ⇌ 4 has been established. For the diradical 4, a heat of formation of 116.2 kcal · m