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Biaryl Synthesis via Pd-Catalyzed Decarboxylative Coupling of Aromatic Carboxylates with Aryl Halides

✍ Scribed by Goossen, Lukas J.; Rodríguez, Nuria; Melzer, Bettina; Linder, Christophe; Deng, Guojun; Levy, Laura M.

Book ID
119978841
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
177 KB
Volume
129
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES

Biaryl and Aryl Ketone Synthesis via Pd-
Biaryl and Aryl Ketone Synthesis via Pd-Catalyzed Decarboxylative Coupling of Carboxylate Salts with Aryl Triflates
✍ Lukas J. Goossen; Christophe Linder; Nuria Rodríguez; Paul P. Lange 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 853 KB

## Abstract A bimetallic catalyst system has been developed that for the first time allows the decarboxylative cross‐coupling of aryl and acyl carboxylates with aryl triflates. In contrast to aryl halides, these electrophiles give rise to non‐coordinating anions as byproducts, which do not interfer