Bi7RhBr8: ein Subbromid mit molekularen [{RhBi7}Br8]-Clustern
✍ Scribed by Dr. Michael Ruck
- Book ID
- 102723173
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 662 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Bi7RhBr8: A Subbromide with Molecular ((RhBi7)Br8) Clusters. -Black platelets of metallic lustre of the title cluster, prepared from the elements at 1270 K, adopt the monoclinic space group P21/n with Z = 4 as shown by single crystal XRD measurements. In the structure RhBi7 form almost ideal pentag
ebenfalls fl-Acetoxyphosphanoxide 6 (98Y0~'~') bzw. 8 (70%, Fp= 175-178°C). Sie ergeben unter einfacher bzw. doppelter Eliminierung von Essigsaure die neuen ungesattigten Phosphanoxide 7 (Kp = 133-142 "C/0.004 mbar) bzw. 9 (Fp=120-122"C).
The dianion of 2,6-bis(diethylamino)-3,4,7,8-tetrahydro-1,3,5,7-tetraazafulvalene-4,8-dithione (1-2 H + ) reacts with the chloro-bridged platinum(II)-complex [(Et 3 P)PtCl 2 ] 2 to give a dark green (N,S)-bischelate (Et 3 P)(Cl)Pt(1-2 H + )Pt(Cl)(PEt 3 ) (2). Spectroscopic data and a 1 H-/ 1 H-2D-CO