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Beyond the Aza-Morita−Baylis−Hillman Reaction: Lewis Base-Catalyzed Reactions of N-Boc-imines with Ethyl 2,3-Butadienoate

✍ Scribed by Guan, Xiao-Yang; Wei, Yin; Shi, Min


Book ID
115499082
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
824 KB
Volume
74
Category
Article
ISSN
0022-3263

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## Abstract A series of polyether dendritic chiral phosphine Lewis bases was synthesized, and successfully applied to the asymmetric aza‐Morita–Baylis–Hillman reaction of __N__‐sulfonated imines (__N__‐arylmethylidene‐4‐methylbenzenesulfonamides) with methyl vinyl ketone (MVK), ethyl vinyl ketone (