𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Benzyllithium Compounds and (Lithiomethyl)hetarenes

✍ Scribed by J. Norm Reed

Book ID
101999140
Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Chiral organometallic reagents, XII. On
Chiral organometallic reagents, XII. On the racemization of α-hetero-substituted benzyllithium compounds
✍ Ahlbrecht, Hubertus ;Harbach, Jürgen ;Hoffmann, Reinhard W. ;Ruhland, Thomas 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 645 KB

## Abstract Benzyllithium compounds carrying a benzylthio substituent (6), a benzylseleno substituent (8), and an isopropyl(methyl)amino substituent (14) have been generated. Racemization barriers have been determined in THF by monitoring the coalescence of signals of diastereotopic groups in the ^

Chiral Organometallic Reagents, VIII. On
Chiral Organometallic Reagents, VIII. On the Configurational Stability of α-Hetero-Substituted Benzyllithium Compounds
✍ Hoffmann, Reinhard W. ;Rühl, Thomas ;Harbach, Jürgen 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 602 KB

## Abstract A test based on kinetic resolution was applied to probe the configurational stability of various α‐substituted benzyllithium compounds 1. It was found that the trimethylsilyl‐ (1b), phenylsulfenyl‐ (1c), and the phenylselenyl‐substituted (1d) benzyllithium compounds enantiomerized more