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Benzylic hydrogen atom abstraction utilizing diethyl bromomalonate as a radical source

โœ Scribed by Truksa, Scott V.; Nibler, Alan; Schatz, Bruce S.; Krosley, Kevin W.; Gleicher, Gerald Jay


Book ID
121416697
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
537 KB
Volume
57
Category
Article
ISSN
0022-3263

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Nitrogen Atom Transfer to Alkenes Utilizing Chloramine-T as a Nitrogen Source. -Readily available and inexpensive chloramine-T (II) is found to undergo a Cu(I)-catalyzed reaction with unfunctionalized alkenes in anhydrous acetonitrile providing N-tosyl aziridines in moderate yield. -