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Benzyl 2-deoxy-2-(3,5-di-tert-butylsalicylamino)-α-d-glucopyranoside

✍ Scribed by Burkhardt, Anja ;Buchholz, Axel ;Görls, Helmar ;Plass, Winfried

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
194 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 28 H 41 NO 6 , was obtained by reduction of benzyl 2-deoxy-2-(3,5-di-tert-butylsalicylideneamino)--dglucopyranoside. The benzyl substituent is in an axial position, whereas the 3,5-di-tert-butylsalicylamino substituent and the hydroxyl groups are in equatorial positions. The enantiomerically pure title compound is a potential O,N,O-chelate ligand suitable as a precursor for chiral transition metal complexes. The absolute configuration was determined by NMR experiments.

📜 SIMILAR VOLUMES

Regioselective polycondensation of benzy
Regioselective polycondensation of benzyl 2-amino-2-deoxy-α-D-glucopyranoside hydrochloride with carbon dioxide
✍ J. Kadokawa; T. Horiguchi; E. Sunaga; M. Karasu; H. Tagaya; K. Chiba 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 369 KB 👁 1 views

This paper reports the polycondensation of benzyl 2-amino-2-deoxy-a-o-glucopyranoside hydrochloride (1) with carbon dioxide using the triphenylphosphine/carbon tetrachlorideDBU system as a condensing agent to give poly(urethane) (2). The polycondensation of 1 with COz was carried out in DMF solvent

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✍ Nacario, Ruel C. ;Lowary, Todd L. ;McDonald, Robert 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 199 KB

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