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tert-Butyl 6-O-benzyl-2,2-di­chloro-2,5-di­deoxy-4-O-methyl-α-d-ribo-oct-3-pyran­ulosonate

✍ Scribed by Gainsford, Graeme J. ;Tyler, Peter C.


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
199 KB
Volume
59
Category
Article
ISSN
1600-5368

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Electrophile-mediated cyclizations of 6-
✍ Fillmore Freeman; Kirk D. Robarge 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 633 KB

## Electrophile (bromine, iodine, mercuric acetate, mercuric trifluoroacetate, phenylselenyl chloride)-mediated cyclization of 6-0-benzyl-1,2-dideoxy-3,4-0isopropylidene-D-ribo-hex-l-enitol (2) led exclusively to l-substituted derivatives of 2,5-anhydro-6-0-benzyl-3,4-O-isopropylidene-D-altro-hex