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Benzoylation of Ethyl Benzoylacetate in the Presence of Various Tertiary Amines 1

โœ Scribed by Wright, Paul E.; McEwen, William E.


Book ID
121267959
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
427 KB
Volume
76
Category
Article
ISSN
0002-7863

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Selective benzoylation of primary amines
โœ Tao Wang; Zhongxing Zhang; Nicholas A. Meanwell ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 120 KB

Compounds containing both primary and secondary amine moieties in the same molecule were treated sequentially with two equivalents of n-butyllithium at room temperature, two equivalents of TMSCI, one equivalent of nbutyllithium and one equivalent of benzoyl chloride, to afford mono-benzoylated diami