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Benzotriazole-Mediated Synthesis of 2,3-Disubstituted Allylic Alcohols

โœ Scribed by Kang, Yoon Ho; Lee, Chang Jae; Kim, Kyongtae


Book ID
126161708
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
70 KB
Volume
66
Category
Article
ISSN
0022-3263

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A stereoselective synthesis of ฮฒ,ฮณ-disub
โœ Mitsuhisa Tamura; Gohu Suzukamo ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 190 KB

Reaction of alkyllithiums 1 with isoprene epoxide 2 gives B,y-disubstituted allylic alcohols 2 of Z-configuration. The reaction of \*-lithiotricyclene as alkyllithium gives o-santalol 5, which is one of the main constituents in East Indian sandalwood oil.