Benzodiazepine analogues. Part 21. 13C NMR analysis of benzoxathiepine derivatives
β Scribed by Aifheli C. Gelebe; Perry T. Kaye; Rosalyn Klein; Joyce D. Sewry; Andrew G. Soper
- Book ID
- 102532084
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 97 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0749-1581
- DOI
- 10.1002/mrc.1649
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β¦ Synopsis
Abstract
The influence of substituents and structure on the ^13^C NMR spectra of four series of benzoxathiepine derivatives has been investigated. Signal assignments in the ^13^C NMR spectra have been facilitated by the use of several predictive methods, permitting comparison of their relative efficacy. Copyright Β© 2005 John Wiley & Sons, Ltd.
π SIMILAR VOLUMES
13C NMR spectra of 1,4-and 1,5-benzoheterazepinones and their tetrazolo derivatives, prepared by the Schmidt rearrangement of Γavanone analogues, are reported. The e β ects of the C-ring heteroatoms on the 13C NMR chemical shifts of the ring-expanded products were found to be of diagnostic value in d
Selected 1,4-and 1,5-benzoheterazepinones, prepared by the Schmidt rearrangement of flavanone analogues, were converted to the corresponding thiolactam derivatives using phosphorus pentasulfide. The proton and carbon chemical shifts of the thiolactam derivatives are compared with those of their lact