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Benzocrown derivatives as ionophores for alkali cations, I synthesis of urethane- and urea-linked mono- and bis-crown ethers

✍ Scribed by Töke, László ;Bitter, István ;Ágai, Béla ;Csongor, Éva ;Tóth, Klára ;Lindner, Ernő ;Horváth, Mária ;Harfouch, Salman ;Pungor, Ernő

Publisher: John Wiley and Sons
Year: 1988
Tongue: English
Weight: 488 KB
Volume: 1988
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.198819880408

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✦ Synopsis

Nvw nicino-and his-benzocrown ethers (5-28 and 29-48) with ciiffccrcnt substitucnts iind connccting chains wcrc prepared with thc aini to dcvclop novel alkali cation-rransport mediators fur hinlogic;il systems. The alkali cation sclectivitics of thc titlc coiiipounds wcrt' dctcrrnined in ion-sclective membrane elcctrodcs. Kcmarkable potiissiurn selectivity was observed with scvcral his-(knzo-1 ~-L.mwn-jjurerhanes.

'H-NMR data of some representative derivatives are summarized in Table 6.

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