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Behaviour of [Ti2(OEt)8Cl]2Mg2(μ-Cl)2 as catalyst component in the Ziegler—Natta polymerization of α-olefins and diolefins

✍ Scribed by U. Zucchini; T. Dall'Occo; A. Angelini


Book ID
103694056
Publisher
Elsevier Science
Year
1993
Weight
635 KB
Volume
82
Category
Article
ISSN
0304-5102

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Cationic transannular polymerization of
✍ Efthymios P. Bokaris; Michael G. Siskos; Antonios K. Zarkadis 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 302 KB

The cationic transannular polymerization of cis,cis-l,5-cyclooctadiene (COD) initiated by Ziegler-Natta catalysts of the type Cp2MCI: (M = Ti, Zr, HI) with various alkylaluminium compounds, such as Et3A1, Et2AIC1 and Et3A12CI 3, was studied. The order of activity of these catalysts depends on the me