Cationic transannular polymerization of
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Efthymios P. Bokaris; Michael G. Siskos; Antonios K. Zarkadis
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Article
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1992
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Elsevier Science
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English
⚖ 302 KB
The cationic transannular polymerization of cis,cis-l,5-cyclooctadiene (COD) initiated by Ziegler-Natta catalysts of the type Cp2MCI: (M = Ti, Zr, HI) with various alkylaluminium compounds, such as Et3A1, Et2AIC1 and Et3A12CI 3, was studied. The order of activity of these catalysts depends on the me